If you are having audio problems while using Skype on Ubuntu, first check to ensure that sound is
working on your system and that your microphone and speaker volume
levels are high enough. If you cannot hear
yourself using the Skype Echo Sound Test, its possible that pavucontrol is not installed on your system. To install it, use the command :
Restart Skype. Now the audio should work fine.
sudo apt-get install pavucontrol
Restart Skype. Now the audio should work fine.